Happy Atheist Forum

General => Science => Topic started by: Recusant on December 22, 2021, 07:45:23 PM

Title: "Just One Word: Microplastics"
Post by: Recusant on December 22, 2021, 07:45:23 PM
Harry Shearer has been doing a radio show for nearly 40 years. I've been listening to it off and mostly on for nearly as long. Shearer is the bassist Derek Smalls in Spinal Tap, and voices a number of characters on The Simpsons; he's been in many other things as well. "Le Show (https://harryshearer.com/le-show/)" is now also a podcast and available on Shearer's site at the link, for those who enjoy such things.

It's a splendid production: Shearer reads various news items, plays songs and vignettes of his own creation, and plays a few selected cuts of music. I read that and it sounds boring, but you might enjoy it if you give it a chance. One of the recurring news segments is News of Microplastics. Fascinating stuff; part of the world our species has made for itself. This to acknowledge that many of the posts in this thread will be gleaned from Shearer's work. I apologise in advance for the fact that most of the items won't be cheery.

For instance, a paper which shows that microplastics can cross the blood/brain barrier in mammals. In addition, the microplastics appear to cause some apoptosis (https://en.wikipedia.org/wiki/Apoptosis) in brain cells.

"Successful identification of the cause and cellular physiology of apoptosis caused by microplastics introduced into the brain" | EurekAlert (https://www.eurekalert.org/news-releases/935795)

QuotePlastic waste, amounting to 8 million tons annually, turns into microplastics(MPs) through constant exposure to UV rays and sea waves. These MPs are consumed by lower-level organisms such as plankton, posing a threat to humans at the top of the food chain.

The research team conducted an experiment in which MPs of 2㎛ or less in size were administered orally to mice for 7 days in order to elucidate the hazards of MPs. The team discovered that nano-plastics with the size of 2㎛ or less even passed through the 'blood-brain barrier' that prevents the brain uptake of hazardous substances. It was highly unusual to observe solids such as MPs, passed through the brain-blood-brain barrier.

Additionally, the team also revealed that MPs accumulate in microglial cells in the brain by applying immunohistochemistry. Through the experiments conducted on the MPs of different sizes(0.2㎛, 2㎛, 10㎛), the team was able to confirm that MPs of less than 2㎛ accumulated in the cytoplasm of microglial cells[1] and significantly decreased the cell proliferation ability after several tens of hours. The team explained that microglial cells recognize MPs as an external threat, leading to microglial phagocytosis, which causes apoptosis following changes in cellular morphology.

[Continues . . . (https://www.eurekalert.org/news-releases/935795)]

The paper (https://www.sciencedirect.com/science/article/abs/pii/S0048969721058952?via%3Dihub) is behind a paywall.

QuoteAbstract:

The remarkable increase in plastic usage and widespread microplastic (MP) pollution has emerged as a substantial concern today. Many recent studies have revealed MPs as potentially hazardous substances in mammals. Despite several reports on the impact of small MPs in the brain and behaviors in aquatic animals, it is still unclear how small MPs affect the brain and its underlying cellular physiology in terrestrial animals.

In this study, we investigated the accumulation of polystyrene MPs (PS-MPs) in mouse brain after oral treatment using three types of fluorescent PS-MPs of different sizes (0.2,2 and 10 μm). We found that PS-MPs were deposited in microglial cells of the brain. Following differential treatment of PS-MPs in human microglial HMC-3 cells, we identified changes in cellular morphology, immune responses, and microglial apoptosis induced by phagocytosis of 0.2 and 2 μm PS-MPs.

By analyzing the PS-MP-treated HMC-3 cell transcriptome, we showed that PS-MPs treatment altered the expression of clusters of immune response genes, immunoglobulins, and several related microRNAs. In addition, we confirmed alterations in microglial differentiation marker expression with the activation of NF-κB, pro-inflammatory cytokines and apoptotic markers in PS-MP-treated human microglial cells and in mouse brain. Our findings suggest a potential risk of small PS-MPs in microglial immune activation, which leads to microglial apoptosis in murine and human brains.

[¶ added. - R]


Title: Re: "Just One Word: Microplastics"
Post by: Tank on December 22, 2021, 09:35:40 PM
We're fucked. Again!
Title: Re: "Just One Word: Microplastics"
Post by: Davin on January 05, 2022, 10:42:59 PM
We really have to cut down on plastics use, as well as figuring out how to eliminate a majority of what we've already put out there,
Title: Re: "Just One Word: Microplastics"
Post by: Bad Penny II on January 07, 2022, 12:55:58 PM
Quote from: Davin on January 05, 2022, 10:42:59 PM
We really have to cut down on plastics use, as well as figuring out how to eliminate a majority of what we've already put out there,

Today I saw flour packaged in a plastic bottle
Title: Re: "Just One Word: Microplastics"
Post by: Tank on January 07, 2022, 02:06:36 PM
Quote from: Bad Penny II on January 07, 2022, 12:55:58 PM
Quote from: Davin on January 05, 2022, 10:42:59 PM
We really have to cut down on plastics use, as well as figuring out how to eliminate a majority of what we've already put out there,

Today I saw flour packaged in a plastic bottle

:(
Title: Re: "Just One Word: Microplastics"
Post by: Icarus on January 12, 2022, 12:31:08 AM
It pains me to know that I am one of the participants in this very real problem.

I have no alternative but to buy Peanut butter in plastic containers, Canadian whiskey in plastic containers, my Broccoli and celery is packaged in thin plastic bags, my automobiles, two of them, have large quantities of plastic parts, when I buy something from Amazon it arrives packaged or at least padded with bubble wrap plastic.  Then there are all of those billions of worn auto tires. Auto tires are not entirely plastic, but they do contain some components, including plastics, that are not degradable within our lifetimes. 

I fear that we have blithely shit in our own mess kits.
Title: Re: "Just One Word: Microplastics"
Post by: billy rubin on January 12, 2022, 12:37:41 AM
smuckers peanut butter is the last one marketed in glass.

remember when the peanut butter jars werr marked with volume indicators so when they wrre empty you could use them as measuring utensils?
Title: Re: "Just One Word: Microplastics"
Post by: Icarus on January 13, 2022, 06:48:20 AM
^ Yes, I remember when a lot of the food packaging had some residual home use value.  What the hell, I used to resharpen my razor blades.

When I was a kid, I built crystal radio sets using old Gillette double edge blue blades as the detector. Galena crystals worked better but the blades had some mysterious power to detect radio signals.  Oatmeal boxes, the round ones, were the perfect shapes for winding the wire coils for the radio.

Title: Re: "Just One Word: Microplastics"
Post by: Tank on January 13, 2022, 07:39:05 AM
Tobacco tins for storing different types of little nails, screws etc.
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on March 25, 2022, 06:59:14 AM
We're soaking in it.

"Microplastics found in human blood for first time" | The Guardian (https://www.theguardian.com/environment/2022/mar/24/microplastics-found-in-human-blood-for-first-time)

QuoteMicroplastic pollution has been detected in human blood for the first time, with scientists finding the tiny particles in almost 80% of the people tested.

The discovery shows the particles can travel around the body and may lodge in organs. The impact on health is as yet unknown. But researchers are concerned as microplastics cause damage to human cells in the laboratory and air pollution particles are already known to enter the body and cause millions of early deaths a year.

[. . .]

The scientists analysed blood samples from 22 anonymous donors, all healthy adults and found plastic particles in 17. Half the samples contained PET plastic, which is commonly used in drinks bottles, while a third contained polystyrene, used for packaging food and other products. A quarter of the blood samples contained polyethylene, from which plastic carrier bags are made.

"Our study is the first indication that we have polymer particles in our blood – ​it's a breakthrough result," said Prof Dick Vethaak, an ecotoxicologist at Vrije Universiteit Amsterdam in the Netherlands. "But we have to extend the research and increase the sample sizes, the number of polymers assessed, etc." Further studies by a number of groups are already under way, he said.

[Continues . . . (https://www.theguardian.com/environment/2022/mar/24/microplastics-found-in-human-blood-for-first-time)]

A pre-print version of the paper is available--

"Discovery and quantification of plastic particle pollution in human blood" | Environment International (https://doi.org/10.1016/j.envint.2022.107199)

QuoteAbstract:

Plastic particles are ubiquitous pollutants in the living environment and food chain but no study to date has reported on the internal exposure of plastic particles in human blood. This study's goal was to develop a robust and sensitive sampling and analytical method with pyrolysis double shot - gas chromatography/mass spectrometry and apply it to measure plastic particles ≥700 nm in human whole blood from 22 healthy volunteers.

Four high production volume polymers applied in plastic were identified and quantified for the first time in blood. Polyethylene terephthalate, polyethylene and polymers of styrene (a sum parameter of polystyrene, expanded polystyrene, acetonitrile butadiene styrene etc.) were the most widely encountered, followed by poly(methyl methylacrylate). Polypropylene was analysed but values were under the limits of quantification.

In this study of a small set of donors, the mean of the sum quantifiable concentration of plastic particles in blood was 1.6 µg/ml, showing a first measurement of the mass concentration of the polymeric component of plastic in human blood. This pioneering human biomonitoring study demonstrated that plastic particles are bioavailable for uptake into the human bloodstream. An understanding of the exposure of these substances in humans and the associated hazard of such exposure is needed to determine whether or not plastic particle exposure is a public health risk.
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on March 26, 2022, 05:59:19 AM
Interesting things, maybe even relevant.

"Brazilian biologists 'frightened' at amount of microplastics in Rio marine life" | Reuters (https://www.reuters.com/lifestyle/science/brazilian-biologists-frightened-amount-microplastics-rio-marine-life-2022-03-16/)

QuoteBiologists in Rio de Janeiro studying the presence of microplastics in marine life off the coast of Brazil's postcard city have found that the impact of plastic pollution is far worse than they had feared.

The team of biologists don wetsuits and oxygen canisters to dive into the tropical waters around Rio and sample marine life from the ocean. They then measure the quantity of microplastics found inside the organisms in a laboratory.

Plastic objects which end up in the ocean break down into smaller pieces and can eventually end up inside fish and other creatures, researchers told Reuters.

"I was frightened. I knew I would find some [microplastics] but I never thought it would be that much," said Raquel Neves, a marine biologist at the Federal University of the State of Rio de Janeiro (UNIRIO), who finds the microplastics under a microscope.

[Continues . . . (https://www.reuters.com/lifestyle/science/brazilian-biologists-frightened-amount-microplastics-rio-marine-life-2022-03-16/)]

When I went in search of a paper on this study, I came across a video instead. The article at the link below doesn't mention a paper, nor do the notes for the video. On ResearchGate and Google Scholar I found two scientists quoted in the article, but was unable to find anything from them about microplastics. Maybe there is a paper on this that I've failed to find, or maybe it will be published in due course.

"Mini-documentary about scientific study of the marine environment reveals presence of microplastics in sea creatures" | OceanPact (https://oceanpact.com/en/mini-documentary-about-scientific-study-of-the-marine-environment-reveals-presence-of-microplastics-in-sea-creatures/)

QuoteOn January 26, the Instituto Mar Urbano launched a video called "PlastiTox: A Multi-Integrated Approach to Assessing the Toxicity of Plastic Pollutants to Biota and Coastal Ecosystem Services," as a result of a partnership with UNIRIO and OceanPact to present an unparalleled scientific study about levels of microplastics found in the ocean and in sea creatures off the coast of Rio de Janeiro.

The PlastiTox video was launched in a live online event on the Instituto Mar Urbano's YouTube channel, featuring UNIRIO researchers; the institute's director, Ricardo Gomes; and OceanPact's sustainability director, Fernando Borensztein. After that, the video was posted on all three institutions' social media.

Over the course of three days, the expedition documented in PlastiTox collected samples in Guanabara Bay and around the Tijucas Islands, off the coast of the neighborhood of Barra da Tijuca. The entire project was supported by OceanPact, which provided a manned vessel to help with the research and production of the mini-documentary.

[Continues . . . (https://oceanpact.com/en/mini-documentary-about-scientific-study-of-the-marine-environment-reveals-presence-of-microplastics-in-sea-creatures/)]


* * *


It gets better, it must. Maybe some fatal flaw will be found in the study described below. :lol:

"Microplastics increase the toxicity of organic pollutants in the environment by a factor of 10, study finds" | ScienceDaily (https://www.sciencedaily.com/releases/2022/02/220216112233.htm)

QuoteA new study by Tel Aviv University researchers found that in a marine environment, microplastics absorb and concentrate toxic organic substances and thus increase their toxicity by a factor of 10, which may lead to a severe impact on human health. The study was conducted by Dr. Ines Zucker of the School of Mechanical Engineering and the Porter School of the Environment and Earth Sciences at Tel Aviv University, together with Ph.D. student Andrey Eitan Rubin.

The study was recently published in the journal Chemosphere.

[Continues . . . (https://www.sciencedaily.com/releases/2022/02/220216112233.htm)]

The paper (https://doi.org/10.1016/j.chemosphere.2021.133212) is behind a paywall.

QuoteAbstract:

High levels of persistent contaminants such as microplastics (MPs) and trace organic compounds (TrOCs) in the aquatic environment have become a major threat on the ecosystem and human health. While MP's role as a vector of environmental TrOCs is widely discussed in the literature, the corresponding implications of the interaction between these two compounds on human health (i.e., their joint toxic effect) have not been illustrated.

Using a TrOCs model (Triclosan, TCS) and primary MPs (polystyrene microbeads), this work evaluates the sorption and desorption potential of TCS and MPs in simulated environmental and cellular conditions, respectively, and estimates the single and joint toxicity of these interactions toward human cells (Caco-2).

Surface functionality of the microbeads highly increased their adsorption capacity of TCS, from 2.3 mg TCS for non−functionalized microbeads to 4.6 mg and 6.1 mg TCS per gram of microbeads for amino- and carboxyl-functionalized MPs, respectively. Using non-functionalized MPs, non-specific "hydrophobic-like" interactions and π-π interactions dominated the sorption mechanism of TCS; however, the addition of hydrogen interactions between functionalized microbeads and TCS increased the microbeads' overall sorption capacity.

TCS was desorbed from both functionalized and non-functionalized MPs when changing from environmental conditions to cellular conditions. Desorption was found to be dependent on the matrix complexity and protein content as well as microbead functionality.

Finally, toxicity tests suggested that while low concentrations of TCS and MPs (separately) have minor toxic effect toward Caco-2 cells, TCS-sorbed MPs at similar concentrations have an order of magnitude higher toxicity than pristine MPs, potentially associated with the close interaction of both MP and TCS with the cells. Overall, this study not only elucidates the role of MPs as a TrOC vector, but also demonstrates a realistic scenario in which co-presence of these environmental contaminants poses risks to the environment and human health.

I came across the story in the previous post on my own, but hat tip to Harry Shearer for the two stories in this post.  :toff:
Title: Re: "Just One Word: Microplastics"
Post by: Biggus Dickus on March 27, 2022, 12:13:40 AM
I recall reading about the presence of Microplastics being found in marine life, but I wasn't aware of the direct impact to human health, especially the finding of these Microplastics being found in human blood . This is disturbing indeed.

My fear is that it will be extremely difficult to actually do something about this, especially with regards to possibly regulating plastics in such a way so as to try and limit the impact this type of exposure to not just humans, but all life.

Don't want to bring politics into this, but Republicans here in the US regularly deny climate change, think renewable energy causes cancer, and believe health directives such as eating a more plant-based diet (Vegan) are anti-American, and communistic ideals.

So I worry not enough will be done to try and combat this, regardless of what the science says.

Anyway I do appreciate you turning me on to "LeShow"...I'm enjoying these!
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on March 27, 2022, 05:24:23 AM
Cool! I should post more of the items from his "News of the Godly" segment. Problem is, they're often even more depressing than the microplastics items.  :lol:
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on April 19, 2022, 07:39:12 AM
Akin to microplastics, our species has done a fair job of dispersing perfluoroalkyl and polyfluoroalkyl substances (PFAS) (https://www.niehs.nih.gov/health/topics/agents/pfc/index.cfm) through our environment. Seems that may not have been a great thing. Some goodish news in this thread for once:

"New evidence shows blood or plasma donations can reduce the PFAS 'forever chemicals' in our bodies" | The Conversation (https://theconversation.com/new-evidence-shows-blood-or-plasma-donations-can-reduce-the-pfas-forever-chemicals-in-our-bodies-178771)

QuoteThere is global concern about PFAS because they have been used widely, are persistent in the environment and accumulate in our bodies over time.

There was no way to reduce the amount of PFAS found in the body – until now.

Our new randomised clinical trial, published in the journal JAMA Network Open, has found regularly donating blood or plasma can reduce blood PFAS levels.

[Continues . . . (https://theconversation.com/new-evidence-shows-blood-or-plasma-donations-can-reduce-the-pfas-forever-chemicals-in-our-bodies-178771)]

The paper is open access:

"Effect of Plasma and Blood Donations on Levels of Perfluoroalkyl and Polyfluoroalkyl Substances in Firefighters in Australia" | JAMA Network Open (https://jamanetwork.com/journals/jamanetworkopen/fullarticle/2790905)

QuoteAbstract--Results:

A total of 285 firefighters (279 men [97.9%]; mean [SD] age, 53.0 [8.4] years) were enrolled; 95 were randomly assigned to donate plasma, 95 were randomly assigned to donate blood, and 95 were randomly assigned to be observed.

The mean level of PFOS [perfluorooctane sulfonate] at 12 months was significantly reduced by plasma donation (–2.9 ng/mL; 95% CI, –3.6 to –2.3 ng/mL; P < .001) and blood donation (–1.1 ng/mL; 95% CI, –1.5 to –0.7 ng/mL; P < .001) but was unchanged in the observation group. The mean level of PFHxS [perfluorohexane sulfonic acid] was significantly reduced by plasma donation (–1.1 ng/mL; 95% CI, –1.6 to –0.7 ng/mL; P < .001), but no significant change was observed in the blood donation or observation groups. Analysis between groups indicated that plasma donation had a larger treatment effect than blood donation, but both were significantly more efficacious than observation in reducing PFAS levels.

Title: Re: "Just One Word: Microplastics"
Post by: Dark Lightning on April 19, 2022, 01:13:01 PM
So the donees end up with the PFAs in their systems.  :???:
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on August 26, 2022, 10:16:38 PM
More on the PFAS front:

"Scientists find a simple way to destroy 'forever chemicals' — by beheading them" | Live Science (https://www.livescience.com/pfas-forever-chemicals-broken-down)

QuoteSynthetic compounds known as "forever chemicals" because they never break down in the environment can actually be destroyed — by beheading.

Scientists discovered a simple destruction technique that works on 10 types of these chemicals, known as per- and polyfluoroalkyl substances (PFAS). Researchers hope that the method will expose weaknesses in even more PFAS-class substances, leading to paths for removing these chemicals from drinking water easily and cheaply.

The researchers published their findings in the journal Science (https://www.science.org/doi/10.1126/science.abm8868) on Aug. 18.

[Continues . . . (https://www.livescience.com/pfas-forever-chemicals-broken-down)]
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on October 27, 2022, 09:54:33 PM
Oh yeah, the worms will help us.  ;D

"Plastic-eating worms may offer solution to mounting waste, Stanford researchers discover" | Stanford News Service (https://news.stanford.edu/pr/2015/pr-worms-digest-plastics-092915.html)

QuoteConsider the plastic foam cup. Every year, Americans throw away 2.5 billion of them. And yet, that waste is just a fraction of the 33 million tons of plastic Americans discard every year. Less than 10 percent of that total gets recycled, and the remainder presents challenges ranging from water contamination to animal poisoning.

Enter the mighty mealworm. The tiny worm, which is the larvae form of the darkling beetle, can subsist on a diet of Styrofoam and other forms of polystyrene, according to two companion studies co-authored by Wei-Min Wu, a senior research engineer in the Department of Civil and Environmental Engineering at Stanford. Microorganisms in the worms' guts biodegrade the plastic in the process – a surprising and hopeful finding.

"Our findings have opened a new door to solve the global plastic pollution problem," Wu said.

[Continues . . . (https://news.stanford.edu/pr/2015/pr-worms-digest-plastics-092915.html)]

Papers are behind a paywall.
Title: Re: "Just One Word: Microplastics"
Post by: Asmodean on October 28, 2022, 07:21:37 AM
QuoteConsider the plastic foam cup. Every year, Americans throw away 2.5 billion of them. And yet, that waste is just a fraction of the 33 million tons of plastic Americans discard every year. Less than 10 percent of that total gets recycled, and the remainder presents challenges ranging from water contamination to animal poisoning.

The above is misleading. It proposes a dichotomy between recycling and various degrees of doom. There is a third option; burn it for energy. The USA - the example they use - does that, so what percentage of plastic waste gets burned? Would increasing that bracket be a viable strategy in combatting the problem that the "eternal" plastics present?
Title: Re: "Just One Word: Microplastics"
Post by: Tank on October 28, 2022, 09:20:00 AM
Sweden has run out of rubbish to burn to create power. It is importing rubbish now. The up side is the removal of plastic from the system. The down side is this process is far from carbon neutral in that the plastic originates mostly from oil. So a bit of a poison challis.
Title: Re: "Just One Word: Microplastics"
Post by: Asmodean on October 28, 2022, 09:27:03 AM
In a way. Still, we do need energy to keep them proverbial cogs turning. With the electrification of industry and transportation, what reliable short-to-mid term solutions to the increased demand are there, except for coal, oil and gas?
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on November 03, 2022, 06:27:43 AM
After some at least mildly positive items, back to the prevalent theme of the thread . . .

"How much microplastic do whales eat? Up to 10 million pieces per day, research finds" | Phys.org (https://phys.org/news/2022-11-microplastic-whales-million-pieces-day.html)

QuoteThe largest animals ever known to have lived on Earth ingest the tiniest specks of plastic in colossal amounts, Stanford University scientists have found.

ublished in Nature Communications, the study focuses on blue, fin, and humpback whales and their consumption of plastic fragments no bigger than a few grains of sand, which are commonly called microplastics. The authors combined measures of microplastic concentrations up and down the water column off the coast of California with detailed logs of where hundreds of whales carrying tracking devices foraged for food between 2010 and 2019.

They found the whales predominantly feed 50 to 250 meters below the surface, a depth that coincides with the highest concentrations of microplastic in the open ocean. The planet's biggest creature—the blue whale—ingests the most plastic, at an estimated 10 million pieces per day as it feeds almost exclusively on shrimplike animals called krill.

"They're lower on the food chain than you might expect by their massive size, which puts them closer to where the plastic is in the water. There's only one link: The krill eat the plastic, and then the whale eats the krill," said study co-author Matthew Savoca, a postdoctoral scholar at Hopkins Marine Station, Stanford's marine laboratory on the Monterey Peninsula.

[Continues . . . (https://phys.org/news/2022-11-microplastic-whales-million-pieces-day.html)]

The paper is open access:

"Field measurements reveal exposure risk to microplastic ingestion by filter-feeding megafauna" | Nature Communications (https://www.nature.com/articles/s41467-022-33334-5)

QuoteAbstract:

Microparticles, such as microplastics and microfibers, are ubiquitous in marine food webs. Filter-feeding megafauna may be at extreme risk of exposure to microplastics, but neither the amount nor pathway of microplastic ingestion are well understood. Here, we combine depth-integrated microplastic data from the California Current Ecosystem with high-resolution foraging measurements from 191 tag deployments on blue, fin, and humpback whales to quantify plastic ingestion rates and routes of exposure.

We find that baleen whales predominantly feed at depths of 50–250 m, coinciding with the highest measured microplastic concentrations in the pelagic ecosystem. Nearly all (99%) microplastic ingestion is predicted to occur via trophic transfer. We predict that fish-feeding whales are less exposed to microplastic ingestion than krill-feeding whales. Per day, a krill-obligate blue whale may ingest 10 million pieces of microplastic, while a fish-feeding humpback whale likely ingests 200,000 pieces of microplastic. For species struggling to recover from historical whaling alongside other anthropogenic pressures, our findings suggest that the cumulative impacts of multiple stressors require further attention.
Title: Re: "Just One Word: Microplastics"
Post by: Tank on November 03, 2022, 07:27:56 AM
It really is a terrible state of affairs.
Title: Re: "Just One Word: Microplastics"
Post by: Asmodean on November 03, 2022, 01:50:04 PM
I've been reading about India's ban on single use plastics having failed. Shall see if I can find the article in English.

We have most certainly failed here, as while I cannot get a straw that doesn't taste like cardboard with my soft drink, I cannot get a single use package of butter or the like without a plastic box.

As Tom Macdonald once put it, "No more plastic straws wrapped in paper, just paper straws wrapped in plastic." Seen a little broadly and metaphorically, it certainly looks precisely like that.
Title: Re: "Just One Word: Microplastics"
Post by: Tank on November 03, 2022, 05:29:44 PM
Quote from: Asmodean on November 03, 2022, 01:50:04 PMI've been reading about India's ban on single use plastics having failed. Shall see if I can find the article in English.

We have most certainly failed here, as while I cannot get a straw that doesn't taste like cardboard with my soft drink, I cannot get a single use package of butter or the like without a plastic box.

As Tom Macdonald once put it, "No more plastic straws wrapped in paper, just paper straws wrapped in plastic." Seen a little broadly and metaphorically, it certainly looks precisely like that.

I have my own set of reusable metal straws which I keep in the glove compartment of my car.
Title: Re: "Just One Word: Microplastics"
Post by: Asmodean on November 03, 2022, 06:24:35 PM
I... May hereby be admitting to having a bunch of plastic straws and like... Washing them.  :sad sigh:
Title: Re: "Just One Word: Microplastics"
Post by: Tank on November 03, 2022, 09:02:25 PM
Quote from: Asmodean on November 03, 2022, 06:24:35 PMI... May hereby be admitting to having a bunch of plastic straws and like... Washing them.  :sad sigh:

Well at least that's not single use.
Title: Re: "Just One Word: Microplastics"
Post by: Icarus on November 04, 2022, 03:21:56 AM
Drilling down to the root cause of the problem: it is caused by people. Too damned many people who use too many straws, plastic bottles, containers, packaging, and even clothing and paints, whiskey bottles, automotive components, and a plethora of other things containing polymeric molecular components.

Those Jesus people were right about the need to refrain from copulation, but they do not preach this need for the reasons that we are herewith confronted.



 
Title: Re: "Just One Word: Microplastics"
Post by: Dark Lightning on November 04, 2022, 03:58:22 AM
Whaaaat? They were told to "Go forth and multiply!"! The "don't do it" part is just to set up sexual tension and guilt for exploitation.

As for the microplastics, I suspect that they will move up the food chain until we are all as plastic as the movie stars. J/K, the plastic part is serious business. I have seen that there are bacteria that eat that stuff, though. Bacteria will get me in the end, anyway. :shrug:
Title: Re: "Just One Word: Microplastics"
Post by: Asmodean on November 04, 2022, 07:06:17 AM
Quote from: Icarus on November 04, 2022, 03:21:56 AMDrilling down to the root cause of the problem: it is caused by people. Too damned many people who use too many straws, plastic bottles, containers, packaging, and even clothing and paints, whiskey bottles, automotive components, and a plethora of other things containing polymeric molecular components.

Those Jesus people were right about the need to refrain from copulation, but they do not preach this need for the reasons that we are herewith confronted.
Yes.

It's not just that too many people are, and that too many people use them plastics what get into my whale burger or tuna salad, but it's also how they treat their waste, which I think it is fair enough to call "as cheaply as possible."

There are regions where a sort of landfill economy has emerged, where people collect and sell waste products for money. Were it a bit more profitable, perhaps people would consider not throwing something in the nearest river or on a landfill? Like, the plastic bottle scheme we have around here seems to be working - when you buy a soft drink, you pay a couple of coins for the bottle. Upon returning said bottle, you get them coins back. Even here at work, people collect the empty bottles, then we return them and use the money to buy chocolates for the lounge and stuff like that. It only works because there is incentive - if there was not, we'd all just toss our bottles into the office bins, from which I'm almost certain the road goes straight to the landfill.

Of course, the road to the oceans may be a bit more complex than that. Autosorting and burning combustibles for energy is a thing, still, I think personal incentives may come far without costing the tax payer much.
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on March 21, 2023, 04:46:27 PM
A twinge of nostalgia in this article, unrelated to its subject. Paper was published September of last year, but pop science sites writing about it now...

"Scientists make 'disturbing' find on remote island: plastic rocks" | Phys.org (https://phys.org/news/2023-03-scientists-disturbing-remote-island-plastic.html)

QuoteThere are few places on Earth as isolated as Trindade island, a volcanic outcrop a three- to four-day boat trip off the coast of Brazil.

So geologist Fernanda Avelar Santos was startled to find an unsettling sign of human impact on the otherwise untouched landscape: rocks formed from the glut of plastic pollution floating in the ocean.

Santos first found the plastic rocks in 2019, when she traveled to the island to research her doctoral thesis on a completely different topic—landslides, erosion and other "geological risks."

She was working near a protected nature reserve known as Turtle Beach, the world's largest breeding ground for the endangered green turtle, when she came across a large outcrop of the peculiar-looking blue-green rocks.

Intrigued, she took some back to her lab after her two-month expedition.

Analyzing them, she and her team identified the specimens as a new kind of geological formation, merging the materials and processes the Earth has used to form rocks for billions of years with a new ingredient: plastic trash.

"We concluded that human beings are now acting as a geological agent, influencing processes that were previously completely natural, like rock formation," she told AFP.

"It fits in with the idea of the Anthropocene, which scientists are talking about a lot these days: the geological era of human beings influencing the planet's natural processes. This type of rock-like plastic will be preserved in the geological record and mark the Anthropocene."

...

[Santos] found similar rock-like plastic formations had previously been reported in places including Hawaii, Britain, Italy and Japan since 2014.

But Trindade island is the remotest place on the planet they have been found so far, she said.

She fears that as the rocks erode, they will leach microplastics into the environment and further contaminate the island's food chain.

[Continues . . . (https://phys.org/news/2023-03-scientists-disturbing-remote-island-plastic.html)]

Seems like these "stones" would have been formed from microplastics in the first place, but perhaps not. The paper (https://www.sciencedirect.com/science/article/abs/pii/S0025326X22007135) is behind a paywall.

QuoteAbstract:

Continuous input of plastic litter in ocean and coastal environments achieved alarming levels that are exposing new settings in natural systems. While novel plastic debris pollution, with rock-like appearance, has been reported worldwide, fundamentally geological analyses are still lacking.

We surveyed the first occurrence of multiple associated plastic debris on a single outcrop located in a remote site (Trindade Island, SE Atlantic Ocean). Even though all plastic debris forms consisted of polypropylene and polyethylene, through a sedimentary approach (cross section, macro, and micro analyses) distinct types were identified.

We detected plastiglomerates, geogenic analogous to conglomerates, divided into in situ and clastic types, and formed over beach sediment. We identified plastistones as a new type with homogeneous composition (lacking incorporated materials), geogenic-looking igneous rocks, divided into in situ and clastic types, and formed over rock surfaces. We linked pyroplastics, geogenic analogous to clasts, to clastic plastiglomerates/plastistones, therefore representing clastic types of plastic debris forms. This association was correlated in a depositional system model, which suggests that plastic debris forms are rock synthetic equivalents in which humans act as depositional and post-depositional agents.
Title: Re: "Just One Word: Microplastics"
Post by: Dark Lightning on March 21, 2023, 04:52:56 PM
I just read about this! That's disgusting. This is probably how we end up trashing the planet (and dying), not global warming.
Title: Re: "Just One Word: Microplastics"
Post by: Tank on March 22, 2023, 09:00:16 AM
That's incredible and equally disturbing.
Title: Re: "Just One Word: Microplastics"
Post by: Tank on April 22, 2023, 04:42:51 PM
Study shows how tiny plastic particles manage to breach the blood-brain barrier (https://phys.org/news/2023-04-tiny-plastic-particles-breach-blood-brain.html)

QuotePublished in the journal Nanomaterials, the study was carried out in an animal model with oral administration of MNPs, in this case polystyrene, a widely-used plastic which is also found in food packaging. Led by Lukas Kenner (Department of Pathology at MedUni Vienna and Department of Laboratory Animal Pathology at Vetmeduni) and Oldamur Hollóczki (Department of Physical Chemistry, University of Debrecen, Hungary) the research team was able to determine that tiny polystyrene particles could be detected in the brain just two hours after ingestion.

More research. And no good news.
Title: Re: "Just One Word: Microplastics"
Post by: MarcusA on April 24, 2023, 08:30:21 AM
On human waste in general: it goes on. Life goes on but probably not for very  much longer at the rate that humans are laying waste to the planet, our home.
Title: Re: "Just One Word: Microplastics"
Post by: Icarus on May 05, 2023, 09:24:26 PM
Quote from: MarcusA on April 24, 2023, 08:30:21 AMOn human waste in general: it goes on. Life goes on but probably not for very  much longer at the rate that humans are laying waste to the planet, our home.

One more hazard to add to the list. We have previously had only sparse information about "Nurdles".

https://getpocket.com/explore/item/nurdles-the-worst-toxic-waste-you-ve-probably-never-heard-of?utm_source=pocket-newtab
Title: Re: "Just One Word: Microplastics"
Post by: Dark Lightning on May 06, 2023, 12:35:39 AM
Yeah, I suspect that plastics are going to be our downfall before global warming. Sad, because that crap could take everything out that doesn't adapt to it.
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on May 06, 2023, 12:43:22 AM
Apparently I've neglected to mention nurdles in this thread before, but as somebody who follows the topic, sadly I'm familiar with them. Probably they're a significant component of the North Pacific Garbage Patch. More macro than micro, but definitely relevant in this thread.

"Converging ocean currents bring floating life and garbage together" | Phys.org (https://phys.org/news/2023-05-converging-ocean-currents-life-garbage.html)

QuoteThe North Pacific "Garbage Patch" is home to an abundance of floating sea creatures, as well as the plastic waste it has become famous for, according to a study by Rebecca Helm from Georgetown University, U.S., and colleagues. The paper is published in the open access journal PLOS Biology.

There are five main oceanic gyres—vortexes of water where multiple ocean currents meet—of which the North Pacific Subtropical Gyre (NPSG) is the largest. It is also known as the North Pacific "Garbage Patch," because converging ocean currents have concentrated large amounts of plastic waste there.

However, many floating ocean creatures, such as jellyfish (cnidarians), snails, barnacles and crustaceans, may also use currents to travel through the open ocean, but little is known about where they live.

The researchers took advantage of an 80-day long-distance swim through the NPSG in 2019 to investigate these floating lifeforms, by asking the sailing crew accompanying the expedition to collect samples of surface sea creatures and plastic waste. The expedition's route was planned using computer simulations of ocean surface currents to predict areas with high concentrations of marine debris.

The team collected daily samples of floating life and waste in the eastern NPSG, and found that sea creatures were more abundant inside the NPSG than on the periphery. The occurrence of plastic waste was positively correlated with the abundance of three groups of floating sea creatures: sea rafts (Velella sp), blue sea buttons (Porpita sp) and violet sea snails (Janthina sp).

[Continues . . . (https://phys.org/news/2023-05-converging-ocean-currents-life-garbage.html)]

The paper is open access:

"High concentrations of floating neustonic life in the plastic-rich North Pacific Garbage Patch" | PLOS Biology (https://journals.plos.org/plosbiology/article?id=10.1371/journal.pbio.3001646)

QuoteAbstract:

Floating life (obligate neuston) is a core component of the ocean surface food web. However, only 1 region of high neustonic abundance is known so far, the Sargasso Sea in the Subtropical North Atlantic gyre, where floating life provides critical habitat structure and ecosystem services.

Here, we hypothesize that floating life is also concentrated in other gyres with converging surface currents. To test this hypothesis, we collected samples through the eastern North Pacific Subtropical Gyre in the area of the North Pacific "Garbage Patch" (NPGP) known to accumulate floating anthropogenic debris.

We found that densities of floating life were higher inside the central NPGP than on its periphery and that there was a positive relationship between neuston abundance and plastic abundance for 3 out of 5 neuston taxa, Velella, Porpita, and Janthina. This work has implications for the ecology of subtropical oceanic gyre ecosystems.
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on November 30, 2023, 10:55:52 PM
Some positive-sounding news on this topic for once.

"Durable plastic pollution easily, cleanly degrades with new catalyst" | Northwestern University (https://news.northwestern.edu/stories/2023/11/durable-plastic-pollution-easily-cleanly-degrades-with-new-catalyst/)

QuoteMany people are familiar with the haunting images of wildlife — including sea turtles, dolphins and seals — tangled in abandoned fishing nets.

The main issue behind Nylon-6, the plastic inside these nets, carpet and clothing, is that it's too strong and durable to break down on its own. So, once it's in the environment, it lingers for thousands of years, littering waterways, breaking corals and strangling birds and sea life.

Now, Northwestern University chemists have developed a new catalyst that quickly, cleanly and completely breaks down Nylon-6 in a matter of minutes — without generating harmful byproducts. Even better: The process does not require toxic solvents, expensive materials or extreme conditions, making it practical for everyday applications.

[Continues . . . (https://news.northwestern.edu/stories/2023/11/durable-plastic-pollution-easily-cleanly-degrades-with-new-catalyst/)]

A pre-print of the paper is available:

"Catalyst Design to Address Nylon Plastics Recycling" | ChemRxiv (https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/6448089f83fa35f8f63ce256/original/catalyst-design-to-address-nylon-plastics-recycling.pdf)

QuoteAbstract:

Rational tailoring of catalytic systems offers highly desirable transformations targeting the growing environmental challenges associated with plastics pollution. For example, the identification of efficient catalysts to address alarming end-of-life Nylon pollution remains underexplored.

Nylon-6 is a non-biodegradable high-performance engineering plastic with centuries of chemical persistence, resulting in millions of tons of waste accumulation. Here we report the rational manipulation of organolanthanide catalyst structure to achieve an exceptionally efficient, solventless, and scalable Nylon-6 depolymerization process, affording monomer ε-caprolactam in ≥99% yield.

Specifically, catalyst Cp*2LaCH(TMS)2 (Cp* = η5-C5Me5, TMS = SiMe3) operates at catalyst loadings as low as 0.2 mol% and temperatures as low as 220 °C. For efficient deconstruction of more recalcitrant commodity Nylon-6 end-of-life articles such as fishing nets, carpets, and clothing, the robust, thermally stable ansa-metallocene catalyst Me2SiCp''2YCH(TMS)2, (Cp'' = η5-C5Me4) effects >99% conversion of these items into ε-caprolactam.

The collected product can be readily re-polymerized to afford pristine Nylon-6 with higher molecular masses and comparable structural regularity, providing a superior upcycling pathway for end-of-life Nylon plastics. Experimental mechanistic studies reveal intriguing and effective depolymerization pathways, such as catalytic intrachain "unzipping" enabled by the catalyst π-ancillary ligand steric constraints. Effective interchain "hopping" mechanisms, as well as chain-end deactivation are also demonstrated and supported by DFT analyses.
Title: Re: "Just One Word: Microplastics"
Post by: Tank on December 01, 2023, 09:08:20 AM
That is good news.
Title: Re: "Just One Word: Microplastics"
Post by: Recusant on February 24, 2024, 04:01:37 AM
Microplastics infiltrating old lake sediments; no longer a good marker for the Age of Humans.

"Buried microplastics complicate efforts to define the Anthropocene" | Nature (https://www.nature.com/articles/d41586-024-00535-5)

QuoteThe presence of microplastics in layers of material that settle at the bottom of lakes might be an unreliable way to determine the onset of the Anthropocene — the geological epoch marking the consequences of human activity on the environment. That is the conclusion of researchers who have shown that tiny plastic particles can infiltrate deep into old sediments.

The date when the Anthropocene began is still being debated. But the presence of microplastics is one of the measures that geologists look at when analysing material from lakes and seas to see whether human activity has made an impact. And microplastic content has also been suggested as a way to date geological sediments.

In a study published [February 21] in Science Advances, researchers looked for plastics in sediment from three lakes in Latvia: Seksu, Pinku and Usmas.

They found 14 types of plastic in sediment samples. In all three of the lakes, the most recent, uppermost sediment layers contained the most plastic particles. But the team also found that smaller, narrower particles had travelled down into much older sediments that formed long before plastic production began in the 1950s. For example, particles of the biodegradable plastics polylactic acid (PLA) and polyhydroxybutyrate (PHB) were found in sediment that is more than 200 years old. The researchers used established techniques to date sediment samples, measuring the amounts of lead isotopes and spheroidal carbon-containing particles that the samples contained.

[Continues . . . (https://www.nature.com/articles/d41586-024-00535-5)]

The paper is open access:

"Downward migrating microplastics in lake sediments are a tricky indicator for the onset of the Anthropocene" | Science Advances (https://www.science.org/doi/10.1126/sciadv.adi8136)

QuoteAbstract:

Plastics are a recent particulate material in Earth's history. Because of plastics persistence and wide-range presence, it has a great potential of being a global age marker and correlation tool between sedimentary profiles.

In this research, we query whether microplastics can be considered among the array of proxies to delimit the Anthropocene Epoch (starting from the year 1950 and above). We present a study of microplastics deposition history inferred from sediment profiles of lakes in northeastern Europe.

The sediments were dated with independent proxies from the present back to the first half of the 18th century. Regardless of the sediment layer age, microplastic particles were found throughout the cores in all sites. Depending on particles' aspect ratio, less elongated particles were found deeper, while more elongated particles and fibers have reduced mobility.

We conclude that interpretation of microplastics distribution in the studied sediment profiles is ambiguous and does not strictly indicate the beginning of the Anthropocene Epoch.
Title: Re: "Just One Word: Microplastics"
Post by: Tank on February 26, 2024, 10:21:38 AM
Good find. Very interesting.
Title: Re: "Just One Word: Microplastics"
Post by: Icarus on March 22, 2024, 01:05:34 PM
This is an article about the cleanest air on earth.  Not unexpectedly, there are particles of plastic in the air, along with all sorts of other contaminants.

https://getpocket.com/explore/item/the-town-with-the-cleanest-air-in-the-world?utm_source=pocket-newtab-en-us (https://getpocket.com/explore/item/the-town-with-the-cleanest-air-in-the-world?utm_source=pocket-newtab-en-us)
Title: Re: "Just One Word: Microplastics"
Post by: Tank on April 01, 2024, 09:38:32 AM
I read that one major source of microplastics are car tires. They erode into dust that get into the air and washed into the oceans. :(
Title: Re: "Just One Word: Microplastics"
Post by: Asmodean on April 03, 2024, 09:27:25 AM
Hmm... :thoughtful:

This does sound plausible, though I run Michelins, whose maker says that their stuff is made from:

Natural rubber: the main component of the tread layers
Synthetic rubber: part of the treads of car, van and 4x4 tires
Carbon black and silica: used as a reinforcing agent to improve durability
Metallic and textile reinforcement cables: the "skeleton" of the tire, forming the geometric shape and providing rigidity.
Numerous chemical agents: for unique properties like low rolling resistance or ultra-high grip

(source: https://www.michelinman.com/auto/auto-tips-and-advice/tires-101/how-are-tires-made )

...So where is the source of the plastics? Or are they referring to the elastomers as such? I suppose that may be sorta-kinda adequate, though elastic is not plastic.

Or do other manufacturers operate with "plastic tyres?"